Bukkit is a developer API - it basically provides hooks and functions that developers can use to plugin to Minecraft.
Craftbukkit is the server component you download that lets these plugins work with the official Minecraft server.
Craftbukkit is not yet a package manager, rather a server wrapper - plugin installation and managed updates are planned through another tool (fill.bukkit.org) but it has not yet been released - Bukkit itself is still under heavy development.
So, to answer your three bullet points:
What Bukkit does that vanilla Minecraft Server does not
Bukkit on it's own does very little - it simply exposes an API that can be used by developers to add functionality to the game
Why people decide to use it over vanilla Minecraft Server
People generally use it because of the additional functionality that can be added through plugins: area protection, a form of economy, the ability to warp throughout the world, and making Minecarts more stable. A quick browse through the Bukkit plugin releases forum will show you some more possibilities.
What plugins do/are for
I think this is answered through the other two - they add additional functionality to the game. :)