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Updated to add the most recent character, Ana, to the list of characters that can not get headshots.
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All weapons with the exception of Pharah, McCree's secondary, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, Ana (on friend or foe), and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

All weapons with the exception of Pharah, McCree's secondary, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

All weapons with the exception of Pharah, McCree's secondary, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, Ana (on friend or foe), and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

added 20 characters in body
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Yuuki
  • 29.9k
  • 26
  • 126
  • 187

All weapons with the exception of Pharah, McCree's secondary, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

All weapons with the exception of Pharah, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

All weapons with the exception of Pharah, McCree's secondary, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.

Source Link
Yuuki
  • 29.9k
  • 26
  • 126
  • 187

All weapons with the exception of Pharah, Junkrat, Mei's primary, Reinhardt, Winston, Zarya, and Symmetra can headshot. Damage reflected by Genji can headshot as well as the initial arrows for each Hanzo's abilities (though the scattered projectiles and dragon themselves cannot). Roadhog's Whole Hog ultimate can headshot. Other abilities and all melee attacks cannot headshot.