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So let's say I have a Mega Absol vs Xatu or something. Both have Magic Bounce. What would happen if Mega Absol used Will-o-wisp?

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Mega Absol would be affected by it and receive a burn. If both pokemon have Magic Bounce, it will only reflect the move once- causing the user to be hit.

Source: Bulbapedia- If two opposing Pokémon have this Ability only the target's Magic Bounce will reflect the move (i.e. the move will only be reflected once).

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    Do note that Will-o-wisp's accuracy is still taken into effect when Magic Bounced - so it has a chance to miss the user
    – Robotnik ♦
    Jan 26 '14 at 16:39

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