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I noticed that the item Metal Cloak is only available once per game/save state and that means you can only evolve a single Scizor or Steelix. Now are there some other items that occur only once per game and that don't require you to steal it from a wild Pokemon to get a second one?

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The items you mean are Evolution-inducing held items. These are often only avalible once in a game. Here is a list: Evolution-inducing held items

Also there are story and basic items you only get once like a bike and so on.

Which Pokémon evolve while holding an item you can see here:

Evolution while hold an item

Evolution while trade and most of them hold an item

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