What can I do to skyrim to allow my character a chance to disarm any opponent with unarmed fists? Can I do it with an enchanted ring or is there a mod that can incorporate this.
In the base game, you can disarm with the Disarm shout, or by using Disarming Bash in the Block tree. Both of these could conceivably be paired with unarmed combat, but it might not be the experience you're looking for.
The Unarmed Warfare mod adds a relevant Unarmed perk:
Disarming Blow (requires rank two in Exhilarating Blows, adds chance to disarm)
In the description of this mod, it suggests using the Way of the Monk mod but that mod doesn't make mention of disarming, and it also appears that development on it has halted.