I followed the instructions from this answer to an absolute t there and it works great. Only thing is that no matter what I try, whenever I double click on the icon for my second account it asks me to enter the password. Whether I have the "Remember my Password" box ticked or not on either account... no matter what combination I use... my PC will only remember 1 account's password (even, if as I said, the box is ticked) Any suggestions?

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    Why not use a password manager instead? – Yuu Feb 1 '19 at 9:26
  • Hi James, I hope you can find a suitable answer there, as there seems to be no native option for Steam to remember more than one password. – Joachim Feb 1 '19 at 12:28