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No.
Paintings are just decoration, they do not spawn anything, in any version of Minecraft.
Source: http://minecraft.gamepedia.com/Painting#Pocket_and_Pi_Editionhttps://minecraft.wiki/w/Painting#Pocket_and_Pi_Edition
Source: http://minecraft.gamepedia.com/Painting#Pocket_and_Pi_Edition
Source: https://minecraft.wiki/w/Painting#Pocket_and_Pi_Edition
